Environmental Chemistry Lab

We provide expertise in analytical and environmental chemistry.

Outreach

Toxic Crusaders: A High School STEM Outreach Program

DTSC continues its mission, “to protect California’s people and environment from harmful effects of toxic substances” by investing in the early education of scientific literacy to provide a foundation of evidence-based thinking to prepare students for careers in STEM as well as to provide the knowledge for students to protect themselves and their communities from environmental contaminants. Our strategy to achieve our outreach mission is through our program, Toxic Crusaders.

Image features a collage of students wearing personal protective equipment as they participate in hands-on activities at the Environmental Chemistry Laboratory in Pasadena.

Overview

Toxic Crusaders is a STEM outreach program that was founded in 2018 to connect students from underserved high schools with hands-on chemistry education. The program is integrated with public school curricula and is offered in two formats: the 6-week program and one-day on-site events. Both program formats feature a full-day on-site event at the Environmental Chemistry Laboratory (ECL) where the students are given a case scenario of a contaminated environmental site or consumer product, and they role-play a day in the life of a scientist. The program is centered around hands-on vocational training to learn practical laboratory skills, quality control, and data analysis. The students are exposed to applied concepts critical to working in any STEM field such as quality control requirements, laboratory safety protocol, and following strict technical procedures.

The program is developed and delivered solely through the volunteer efforts of DTSC staff. Many programs within DTSC are involved with Toxic Crusaders including Hazardous Waste Management (HWM) Safer Consumer Products (SCP), the Office of Environmental Information Management (OEIM), the Office of Environmental Equity (OEE), and Industrial Hygiene (IH). Collaboration between programs has transformed Toxic Crusaders into a wholistic experience for students who learn of the different career trajectories within the department The students have the opportunity to speak with the volunteers throughout the on-site event to gain advice and exposure to a broad range of STEM careers. The outcomes of the program are measured through knowledge assessment surveys administered before and following the program.

Toxic Crusaders was developed with three objectives:

  1. To expose students to a professional laboratory in a hands-on setting,
  2. To empower students with knowledge about toxic chemicals present in their environments and consumer products,
  3. To expose students to a range of fulfilling government careers.

Students from a Toxic Crusaders event performing an experiment and viewing test tubes.Past Toxic Crusader Programs

The 2023 Program

Program Details

The 2023 Toxic Crusaders program spanned five days from October 24th – October 28th serving two high schools located in inner-city Los Angeles, Huntington Park Institute of Applied Medicine, and Orthopedic Hospital Medical Magnet High School. Two chemistry classes from each high school attended, with one class for the on-site curriculum each day. Toxic Crusaders was proud to host an open invite to the community on the fifth day on Saturday October 28th. Fliers were distributed throughout school districts in the greater Los Angeles region drawing the attention of close to 50 students who joined DTSC for the event. A total of 230 students underwent the 2023 program.

Safer Consumer Products (SCP), a program within DTSC, assisted in the development of Toxic Crusaders 2023. The scope of the 2023 program focused on exposure to commonly contaminated products, namely per- and polyfluoroalkyl substances (PFASs) in carpets and rugs as well as toluene in nail products. The popularity of these products connected DTSC’s work to the daily life of most of the students. Three stations comprised the on-site visit with all students cycling through each. Stations 2 and 3 emphasized the quality control procedures needed for each experiment. A summary of the workshop stations is listed in the table below:

Station #ContaminantTaskTechnique
1PFASs

Separate carpet fiber from backing components

Sample preparation for analysis in Station 2

2PFASs

Extraction of PFASs from carpet samples and subsequent analysis

Solid-liquid extraction followed by analysis with liquid chromatography tandem mass spectrometry (LC-MS/MS)

3Toluene

Extraction of toluene from nail polish and subsequent analysis

Purge and trap gas chromatography mass spectrometry (PT-GC-MS)

 

Check out the 2023 Toxic Crusaders Summary Report and stay tuned for future student outreach events!

The 2022-23 Program

Program Details

The 2022-2023 Toxic Crusaders program pivoted from targeting elementary and middle school students to serve students from Huntington Park Institute of Applied Medicine, a local high school located in inner-city Los Angeles. The program was expanded with virtual workshops and two sets of on-site events. The first event was held in November 2022 with the objective to prepare students with background information, quality control requirements, and sampling procedures to ready them for the second visit which focused on laboratory techniques. The scope of the year’s program focused on hexavalent chromium (Cr(VI)) and perfluorooctane sulfonate (PFOS), the latter belong to the class of PFASs. These toxic chemicals are frequently found together at chrome plating facilities as the PFOS is used to suppress Cr(VI) aerosols, the element which becomes the shiny chrome finish we associate with modern industrial and commercial appliances. Los Angeles is a highly polluted region of California with several chrome plating facilities marked for hazardous waste assessment and remediation. Some of these contaminated sites infringe on residential housing in the area, including where some students may live. This scenario was selected to highlight the relevance of DTSC’s work to the students’ communities and the general public:


DTSC received an anonymous complaint of suspicious activities occurring in an abandoned facility. The suspicious activities emitted an unpleasant smell that traveled to nearby residential neighborhoods. The address of the facility was given as 250 S. Noway St., Pasadena, CA 91105. A Google map search of the address shows pictures indicating that it is indeed an abandoned building. In response to the complaint, DTSC Emergency Response Team obtained a warrant to perform assessment of the building on February 22 and 23, 2023. Due to the unknown nature of this complaint, the Emergency Response Team geared up in Level B personal protective equipment. Their objectives in the assessment were:

  • Isolate and contain the building to prevent further activities from occurring.
  • Identify potential hazards in the building.
  • Make observations of what was found at the building but not tamper with potential evidence or interfere with the site characterization.
  • Provide a report with findings and recommendations to the DTSC Investigation Unit for characterization and cleanup of the site.

A summary of the report from the Emergency Response Team provided the following highlights:

  • The building is a large warehouse with an open space floor plan. It appeared to be used to manufacture children’s jewelry and other ornamental objects.
  • At one end of the building portable tables were set up. Children’s jewelry and other silver plumbing fixture objects were found on the tables.
  • The other side of the building had an empty acid bath of dimensions 3 ft. by 4 ft. with no exhaust system over the bath; empty containers labeled with “Fumetrol 140® Mist Suppressant” were found scattered around the acid bath; 3 open drums of liquid were also found near the acid bath.
  • In the middle of the building were machines used to cut, grind, and shave metal and other materials.
  • Dust was observed in the air, on the floor, and on tabletop surfaces.
  • Minimum of Level C personal protective equipment must be worn when entering the premises.

DTSC Investigation Unit created the Toxic Crusader Task Force to investigate and characterize the site. Based on the information in the report, the Task Force Team will plan their investigation accordingly.


A summary of the November 2022 workstations is as follows:

Station #TaskTechnique
1

Prepare to visit contaminated site

Protocol and paperwork for Hazard Appraisal and Recognition Plan (HARP)

2

Learn how and why quality control samples are necessary for analysis

Protocol for quality control samples

3

Prepare students with bench skills

Unit conversions, pipetting technique

4

Listening to concerns of the public

Public relations

5

Presenting findings to the public

Presentation skills, public relations

A summary of the February 2023 workstations is outlined below:

Station #ContaminantTaskTechnique
1Unknown

Site inspection and sampling

Field sampling and following safety and quality protocol

2PFASs

Calibration of PFASs

Calibration curve, liquid chromatography-tandem mass spectrometry (LC-MS/MS)

3PFASs

Sample preparation and analysis of PFASs

Solid phase extraction, liquid chromatography-tandem mass spectrometry

4ALead, cadmium

Preparing samples for metals analysis

Acid digestion

4BChromium VI

Prepare samples for metals analysis with quality control samples

Quality control protocol, liquid chromatography-inductive coupled plasma mass spectrometry (ICP-MS)

5ALead, cadmium

Calibration and analysis of heavy metals

Calibration curve, inductive coupled plasma-optical mission spectroscopy (ICP-OES)

 

View a poster presented at the Association of Public Health Laboratories (APHL) conference.

The 2019 Program

Program Details

The 2019 Toxic Crusaders program served students from the Alhambra Unified School district with children of ages ranging from 6-13 with a full day of on-site immersion at ECL. DTSC’s Industrial Hygiene program joined ECL with volunteers who guided students through hazardous waste sampling protocol. The 2019 program focused on heavy metals in jewelry and paint, as well as the analysis of used motor oil. Relevant laws that protect the citizens of California were provided to the students who used them to assess whether samples qualified as contaminated. Students were invited to roleplay a dumpster diving case scenario with the following roles: sample collector, quality assurance officer, safety officer, photographer, and chemist. The program reflected real world scenarios that the employees of DTSC manage daily:

“As an environmentally conscious student, you walked down the street to meet up with your friends at KT’s Jewelry Store and noticed an employee of FR’s Automobile Oil Change Shop was throwing everything into a trash dumpster. As you walked past FR’s Shop, you noticed paint was peeling off the wall of the shop and you wondered whether the employee should be throwing everything into the trash dumpster. You continued to walk to KT’s Jewelry Store to meet your friends. In the store, you saw all sorts of colorful children’s jewelry. One of your friends wanted to purchase a necklace for her younger sister’s birthday. She wanted a necklace that was sturdy enough to withstand her sister’s biting and throwing. When you heard that your friend’s sister put objects into her mouth, you wondered if the jewelry was safe.

Because of your inquiring mind, you wanted to investigate whether your observations and hypotheses were valid. To help with your investigation, you, the California Environmental Protection Agency (CalEPA), and the Department of Toxic Substances Control (DTSC) put together a Toxic Crusader Task Force to investigate.

Station #ContaminantTaskTechnique
1Motor oil, toxic metals

Sampling trash for illegal disposal

Following Industrial Hygiene protocol for hazardous waste and sample collection

2Toxic metals

Identifying and screening paint and jewelry samples for toxins

X-ray Fluorescence (XRF)

3Toxic metals

Subsampling toxic jewelry

Identification and preparation of component for analysis

4Motor oil

Extraction and analysis of unknown used oil sample

Gas Chromatography Flame Ionization Detector (GC-FID)

5Toxic metals

Acid digestion and analysis

Inductive Coupled Plasma Optical Emission Spectroscopy (ICP-OES)

 

View a photo slide show from the 2019 event.

The 2018 Program

Program Details

The first Toxic Crusaders program was developed in 2018 through a partnership between the Association of Public Health Laboratories (APHL) and the Department of Toxic Substances Control (DTSC). The program targeted a middle school audience, and so a case scenario was written to connect the work of DTSC with the daily lives of student citizens. Students were provided the following case scenario:

A group of students were playing basketball on the school playground. The basketball rolled into the weeds. When the students went to retrieve the ball, they discovered some smelly drums with dead animals by the drums. A student called the School Principal to the scene. The School Principal was referred by the Fire Department to call the California Environmental Protection Agency (CalEPA), the Department of Toxic Substances Control (DTSC) to investigate.”

Students were assigned to the Toxic Crusader Task Force with the following roles: sample collector, quality assurance officer, safety officer, photographer, and chemist. Together, they were tasked to collect evidence samples, to analyze the samples in the laboratory for contaminants, and to determine whether the site is contaminated or not. Industrial Hygiene volunteers guided the students through sample collection protocol, and volunteers from various DTSC programs assisted the preparation and analysis at ECL Pasadena.

Station #ContaminantTaskTechnique
1

Volatile organic compounds (VOCs)

Sampling of VOCs while following Industrial Hygiene quality assurance protocol

Proper use of PPE, utilization of a powered air purifying respirator

2“Toxin K”

Determination of Toxin K in liquid sample

UV absorbance, generating and interpreting a calibration curve

3Toxic metals

Measurement of metals in soil samples

Inductive Coupled Plasma Optical Emission Spectroscopy (ICP-OES)

4Corrosivity

Determination of corrosive material in solid and liquid samples

pH Meter

 

View a photo booklet detailing the 2018 event.

Other Outreach Initiatives

Laboratory Tours & Visits

ECL invites visitors to tour and learn about our state-of-the-art laboratories at our Pasadena and Berkeley locations. Each laboratory is equipped with advanced analytical instruments and staffed with highly trained scientists.

ECL Pasadena hosts a delegation from China’s Environmental Protection Agency.

Chinese Delegation Visit

In September 2017, ECL Pasadena welcomed a delegation of government officials from China’s Environmental Protection Agency. The delegation had the opportunity to tour the Laboratory, learn about advanced analytical instrumentation and methodologies currently used by ECL, and participate in a Q&A session with ECL scientists. The goal of the visit was to promote the sharing of knowledge and different perspectives that can be used for improvement.

ECL opens its doors to other public or private entities that would like to learn more about us.

California for All Logo Gavin Newsom
Office of the Governor


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Yana Garcia Yana Garcia
Secretary for Environmental Protection


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Katherine M. Butler, MPH, DirectorKatherine M. Butler, MPH
Director


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